Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg , Würzburg 97074, Germany.
Mount Allison University , Department of Biochemistry and Chemistry, Sackville, New Brunswick E4L 1G8, Canada.
Chem Rev. 2016 Aug 24;116(16):9091-161. doi: 10.1021/acs.chemrev.6b00193. Epub 2016 Jul 19.
Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.
尽管二硼烷(4)化合物已经为人所知超过 90 年，但直到过去二十年，其化学性质才得到广泛研究。许多有趣的结构特征和反应模式已经出现，更重要的是，这些化合物现在在金属催化和无金属方法中形成 B-C 键和其他过程中都占有重要地位。
