Department of Chemistry and James Franck Institute, The University of Chicago , Chicago, Illinois 60637, United States.
Center for Nanoscale Materials, Argonne National Laboratory , Argonne, Illinois 60439, United States.
J Am Chem Soc. 2016 Aug 10;138(31):9771-4. doi: 10.1021/jacs.6b05862. Epub 2016 Jul 28.
Semiconductor quantum rings are of great fundamental interest because their non-trivial topology creates novel physical properties. At the same time, toroidal topology is difficult to achieve for colloidal nanocrystals and epitaxially grown semiconductor nanostructures. In this work, we introduce the synthesis of luminescent colloidal CdSe nanorings and nanostructures with double and triple toroidal topology. The nanorings form during controlled etching and rearrangement of two-dimensional nanoplatelets. We discuss a possible mechanism of the transformation of nanoplatelets into nanorings and potential utility of colloidal nanorings for magneto-optical (e.g., Aharonov-Bohm effect) and other applications.
半导体量子环具有重要的基础研究意义,因为它们的非平凡拓扑结构产生了新颖的物理性质。同时,对于胶体纳米晶体和外延生长的半导体纳米结构来说,环形拓扑结构很难实现。在这项工作中,我们引入了具有双和三环形拓扑结构的发光胶体 CdSe 纳米环和纳米结构的合成。纳米环是在二维纳米薄片的受控刻蚀和重排过程中形成的。我们讨论了纳米薄片转化为纳米环的可能机制以及胶体纳米环在磁光(例如,阿哈罗诺夫-玻姆效应)和其他应用中的潜在用途。