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基于氧化石墨烯(GO)纳米片与聚苯乙烯微球静电组装的Janus氧化石墨烯(GO)纳米片的制备

Preparation of Janus Graphene Oxide (GO) Nanosheets Based on Electrostatic Assembly of GO Nanosheets and Polystyrene Microspheres.

作者信息

Yang Yongfang, Zhang Lei, Ji Xiaotian, Zhang Lixin, Wang Hefang, Zhao Hanying

机构信息

Institute of Polymer Science and Engineering, Hebei University of Technology, Tianjin, 300130, P. R. China.

Key Laboratory of Functional Polymer Materials, Ministry of Education, Nankai University, Tianjin, 300071, P. R. China.

出版信息

Macromol Rapid Commun. 2016 Sep;37(18):1520-6. doi: 10.1002/marc.201600308. Epub 2016 Jul 22.

Abstract

A facile and versatile method for the synthesis of Janus graphene oxide (GO) nanosheets with different structures is reported. Based on electrostatic assembly, Janus GO nanosheets can be easily functionalized with a template polymer or be defunctionalized by altering the ionic strength. By using this approach, Janus GO nanosheets are prepared successfully with hydrophobic polystyrene chains on one side and hydrophilic poly(2-(dimethylamino)ethyl methacrylate) chains on the other side.

摘要

报道了一种简便通用的合成具有不同结构的氧化石墨烯(GO)纳米片的方法。基于静电组装,氧化石墨烯纳米片可以很容易地用模板聚合物进行功能化,或者通过改变离子强度来去除功能化。通过这种方法,成功制备了一侧带有疏水聚苯乙烯链而另一侧带有亲水聚(甲基丙烯酸2-(二甲氨基)乙酯)链的氧化石墨烯纳米片。

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