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八位学者,跨越五个世纪,共同发现氧气。

Eight sages over five centuries share oxygen's discovery.

机构信息

Professor Emeritus of Anesthesia, University of California, San Francisco, California

出版信息

Adv Physiol Educ. 2016 Sep;40(3):370-6. doi: 10.1152/advan.00076.2016.

Abstract

During the last century, historians have discovered that between the 13th and 18th centuries, at least six sages discovered that the air we breathe contains something that we need and use. Ibn al-Nafis (1213-1288) in Cairo and Michael Servetus (1511-1553) in France accurately described the pulmonary circulation and its effect on blood color. Michael Sendivogius (1566-1636) in Poland called a part of air "the food of life" and identified it as the gas made by heating saltpetre. John Mayow (1641-1679) in Oxford found that one-fifth of air was a special gas he called "spiritus nitro aereus." Carl Wilhelm Scheele (1742-1786) in Uppsala generated a gas he named "fire air" by heating several metal calcs. He asked Lavoisier how it fit the phlogiston theory. Lavoisier never answered. In 1744, Joseph Priestley (1733-1804) in England discovered how to make part of air by heating red calc of mercury. He found it brightened a flame and supported life in a mouse in a sealed bottle. He called it "dephlogisticated air." He published and personally told Lavoisier and other chemists about it. Lavoisier never thanked him. After 9 years of generating and studying its chemistry, he couldn't understand whether it was a new element. He still named it "principe oxigene." He was still not able to disprove phlogiston. Henry Cavendish (1731-1810) made an inflammable gas in 1766. He and Priestley noted that its flame made a dew. Cavendish proved the dew was pure water and published this in 1778, but all scientists called it impossible to make water, an element. In 1783, on June 24th, Lavoisier was urged to try it, and, when water appeared, he realized that water was not an element but a compound of two gases, proving that oxygen was an element. He then demolished phlogiston and began the new chemistry revolution.

摘要

在上个世纪,历史学家发现,在 13 世纪到 18 世纪之间,至少有六位学者发现我们呼吸的空气中含有我们所需的物质。开罗的伊本·纳菲斯(Ibn al-Nafis,1213-1288 年)和法国的迈克尔·塞尔维特(Michael Servetus,1511-1553 年)准确地描述了肺循环及其对血液颜色的影响。波兰的迈克尔·森迪沃吉乌斯(Michael Sendivogius,1566-1636 年)称空气的一部分为“生命之食”,并将其鉴定为加热硝石产生的气体。牛津的约翰·梅奥(John Mayow,1641-1679 年)发现空气中的五分之一是一种特殊气体,他称之为“氮气”。乌普萨拉的卡尔·威廉·舍勒(Carl Wilhelm Scheele,1742-1786 年)通过加热几种金属矿石产生了一种他称之为“火空气”的气体。他询问拉瓦锡这种气体如何符合燃素理论。拉瓦锡从未回答。1744 年,英国的约瑟夫·普里斯特利(Joseph Priestley,1733-1804 年)发现如何通过加热红色汞矿石来制造部分空气。他发现这种空气可以使火焰变亮,并在密封瓶中支持老鼠的生命。他称之为“脱燃素空气”。他发表了这一发现,并亲自告诉了拉瓦锡和其他化学家。拉瓦锡从未感谢过他。在 9 年的生成和研究其化学性质之后,他仍然无法确定这种气体是否是一种新元素。他仍然将其命名为“氧元素”。他仍然无法反驳燃素说。亨利·卡文迪什(Henry Cavendish,1731-1810 年)于 1766 年制造出一种易燃气体。他和普里斯特利注意到,这种气体的火焰会产生露水。卡文迪什证明了露水是纯净的水,并于 1778 年发表了这一发现,但所有科学家都认为不可能制造出水这种元素。1783 年 6 月 24 日,拉瓦锡被敦促尝试制造这种气体,当水出现时,他意识到水不是一种元素,而是两种气体的化合物,证明了氧是一种元素。他随后推翻了燃素说,开始了新的化学革命。

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