钯催化的分子内羰基α-烯丙基化合成 2-环戊烯酮衍生物。
Synthesis of 2-Cyclopentenone Derivatives via Palladium-Catalyzed Intramolecular Carbonyl α-Alkenylation.
机构信息
College of Chemistry and Molecular Engineering, Zhengzhou University , Zhengzhou 450001, People's Republic of China.
出版信息
Org Lett. 2016 Aug 5;18(15):3914-7. doi: 10.1021/acs.orglett.6b01955. Epub 2016 Jul 27.
PMID:27463262
Abstract
2-Cyclopentenone derivatives have been efficiently synthesized from 5-bromo-5-hexen-2-ones via palladium-catalyzed intramolecular carbonyl α-alkenylation followed by double-bond migration under mild reaction conditions.
摘要
2-环戊烯酮衍生物已通过钯催化的分子内羰基α-烯丙基化反应，然后在温和的反应条件下进行双键迁移，从 5-溴-5-己烯-2-酮高效合成。
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