Senthil Kumar Ponnusamy, Saravanan Anbalagan, Anish Kumar Kodyingil, Yashwanth Ramesh, Visvesh Sridharan
Department of Chemical Engineering, SSN College of Engineering, Chennai - 603110, India.
IET Nanobiotechnol. 2016 Aug;10(4):244-53. doi: 10.1049/iet-nbt.2015.0087.
In the present study, a novel activated carbon was prepared from low-cost eucalyptus seeds, which was utilised for the effectively removal of toxic zinc from the water/wastewater. The prepared adsorbent was studied by Fourier transform infrared spectroscopy and scanning electron microscopic characterisation studies. Adsorption process was experimentally performed for optimising the influencing factors such as adsorbent dosage, solution pH, contact time, initial zinc concentration, and temperature for the maximum removal of zinc from aqueous solution. Adsorption isotherm of zinc removal was ensued Freundlich model, and the kinetic model ensued pseudo-second order model. Langmuir monolayer adsorption capacity of the adsorbent for zinc removal was evaluated as 80.37 mg/g. The results of the thermodynamic studies suggested that the adsorption process was exothermic, thermodynamically feasible and impulsive process. Finally, a batch adsorber was planned to remove zinc from known volume and known concentration of wastewater using best obeyed model such as Freundlich. The experimental details showed the newly prepared material can be effectively utilised as a cheap material for the adsorption of toxic metal ions from the contaminated water.
在本研究中,一种新型活性炭由低成本的桉树种籽制备而成,用于有效去除水/废水中的有毒锌。通过傅里叶变换红外光谱和扫描电子显微镜表征研究对制备的吸附剂进行了研究。通过实验进行吸附过程,以优化影响因素,如吸附剂用量、溶液pH值、接触时间、初始锌浓度和温度,以实现从水溶液中最大程度去除锌。锌去除的吸附等温线遵循弗伦德里希模型,动力学模型遵循准二级模型。该吸附剂对锌去除的朗缪尔单层吸附容量评估为80.37 mg/g。热力学研究结果表明,吸附过程是放热的、热力学可行的且是自发过程。最后,计划使用弗伦德里希等最符合的模型,从已知体积和已知浓度的废水中去除锌的间歇式吸附器。实验细节表明,新制备的材料可有效用作从受污染水中吸附有毒金属离子的廉价材料。