McKeown Paul, Davidson Matthew G, Kociok-Köhn Gabriele, Jones Matthew D
Doctoral Training Centre in Sustainable Chemical Technologies, University of Bath, Bath BA2 7AY, UK and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK.
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK.
Chem Commun (Camb). 2016 Aug 16;52(68):10431-4. doi: 10.1039/c6cc05795k.
We report the rationalised design of aluminium initiators and their application for ROP of rac-lactide (rac-LA). A very minor change to the ligand backbone (imine reduction) to give secondary amines was found to have a dramatic effect on activity and selectivity with isotactic PLA being realised.
我们报道了铝引发剂的合理设计及其在消旋丙交酯（rac-LA）的开环聚合反应中的应用。研究发现，对配体主链进行非常微小的改变（亚胺还原以生成仲胺）会对活性和选择性产生显著影响，从而实现了等规聚乳酸的合成。
