Peng Jin-Bao, Qi Xinxin, Wu Xiao-Feng
Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, Zhejiang Province, 310018, P.R. China.
Leibniz-Institut für Katalyse e.V. an der, Universität Rostock, Albert-Einstein-Strasse 29a, 18059, Rostock, Germany.
ChemSusChem. 2016 Sep 8;9(17):2279-83. doi: 10.1002/cssc.201600625. Epub 2016 Aug 4.
Dyes can CO do it: Organic dyes and pigments are usually applied in textile dyeing, which can be dated back to the Neolithic period. Interestingly, the possibility to use organic dyes as photoredox catalysts has also been noticed by organic chemists and applied in organic synthesis. Carbonylation reactions as a powerful procedure in carbonyl-containing compound preparation have also been studied. In this manuscript, the recent achievements in using organic dyes as visible-light sensitizers in carbonylation chemistry are summarized and discussed.
有机染料和颜料通常用于纺织品染色,这可以追溯到新石器时代。有趣的是,有机化学家也注意到了将有机染料用作光氧化还原催化剂的可能性,并将其应用于有机合成。羰基化反应作为制备含羰基化合物的一种强大方法也得到了研究。在本手稿中,总结并讨论了在羰基化化学中使用有机染料作为可见光敏化剂的最新成果。