Centre for Process Systems Engineering, Imperial College London, London SW7 1NA, UK.
Faraday Discuss. 2016 Oct 20;192:241-250. doi: 10.1039/c6fd00051g.
In order to mitigate climate change to no more than 2 °C, it is well understood that it will be necessary to directly remove significant quantities of CO, with bioenergy CCS (BECCS) regarded as a promising technology. However, BECCS will likely be more costly and less efficient at power generation than conventional CCS. Thus, approaches to improve BECCS performance and reduce costs are of importance to facilitate the deployment of this key technology. In this study, the impact of biomass co-firing rate and biomass moisture content on BECCS efficiency with both post- and oxy-combustion CO capture technologies was evaluated. It was found that post-combustion capture BECCS (PCC-BECCS) facilities will be appreciably less efficient than oxy-combustion capture BECCS (OCC-BECCS) facilities. Consequently, PCC-BECCS have the potential to be more carbon negative than OCC-BECCS per unit electricity generated. It was further observed that the biomass moisture content plays an important role in determining the BECCS facilities' efficiency. This will in turn affect the enthalpic content of the BECCS plant exhaust and implies that exhaust gas heat recovery may be an attractive option at higher rates of co-firing. It was found that there is the potential for the recovery of approximately 2.5 GJ per t at a temperature of 100 °C from both PCC-BECCS and OCC-BECCS. On- and off-site applications for this recovered heat are discussed, considering boiler feedwater pre-heating, solvent regeneration and district heating cases.
为了将气候变化幅度控制在 2°C 以内,人们已经充分认识到,有必要直接去除大量的二氧化碳,而生物质能碳捕获与封存(BECCS)被认为是一种很有前途的技术。然而,BECCS 在发电方面的成本可能比传统的碳捕获要高,效率也更低。因此,提高 BECCS 性能和降低成本的方法对于促进这项关键技术的部署非常重要。在这项研究中,评估了生物质混烧率和生物质水分含量对后燃烧和氧燃烧 CO 捕获技术的 BECCS 效率的影响。结果发现,后燃烧捕获 BECCS(PCC-BECCS)设施的效率将明显低于氧燃烧捕获 BECCS(OCC-BECCS)设施。因此,PCC-BECCS 每单位发电量可能比 OCC-BECCS 具有更大的负碳潜力。进一步观察到,生物质水分含量在确定 BECCS 设施的效率方面起着重要作用。这反过来又会影响 BECCS 工厂废气的焓值,这意味着废气热回收在更高的混烧率下可能是一个有吸引力的选择。结果发现,从 PCC-BECCS 和 OCC-BECCS 中,在 100°C 的温度下,每 t 大约有 2.5 GJ 的热量可以回收。考虑到锅炉给水泵预热、溶剂再生和区域供热等情况,讨论了这种回收热量的现场和场外应用。