Suzuki Kosuke, Hanaya Takumi, Sato Rinta, Minato Takuo, Yamaguchi Kazuya, Mizuno Noritaka
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Chem Commun (Camb). 2016 Aug 23;52(70):10688-91. doi: 10.1039/c6cc05284c.
A hexanuclear mixed valence tin oxide cluster Sn3(2+)Sn3(4+)O15 was successfully synthesized by the solution-state selective oxidation of a tin oxide cluster Sn6(2+)O12 within trivacant lacunary polyoxometalates, where lone pairs on the Sn(2+) species acted as stereochemically active sites.
通过在三缺位的缺位多金属氧酸盐中对氧化锡簇Sn6(2+)O12进行溶液态选择性氧化，成功合成了一种六核混合价态氧化锡簇Sn3(2+)Sn3(4+)O15，其中Sn(2+)物种上的孤对电子充当立体化学活性位点。
