Hanaya Takumi, Suzuki Kosuke, Sato Rinta, Yamaguchi Kazuya, Mizuno Noritaka
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Dalton Trans. 2017 Jun 13;46(23):7384-7387. doi: 10.1039/c7dt01587a.
Three types of heterometallic bismuth-tungsten oxide nanoclusters were successfully synthesized by the reactions of lacunary silicotungstates (trivacant [A-α-SiWO] and divacant [γ-SiWO]) and Bi in organic solvents. Lone pairs on Bi acted as structure-directing groups in these nanoclusters.
通过缺位硅钨酸盐（三缺位[A-α-SiWO]和二缺位[γ-SiWO]）与铋在有机溶剂中的反应，成功合成了三种类型的异金属铋钨氧化物纳米团簇。铋上的孤对电子在这些纳米团簇中充当结构导向基团。
