Janssen Bastian, Lutter Michael, Alnasr Hazem, Krossing Ingo, Jurkschat Klaus
Lehrstuhl für Anorganische Chemie II Fakultät Chemie und Chemische Biologie TU Dortmund 44221 Dortmund Germany.
Institut für Anorganische und Analytische Chemie Albert-Ludwigs Universität Freiburg Albertstr. 21 79104 Freiburg i. Br. Germany.
ChemistryOpen. 2016 Jun 15;5(4):319-24. doi: 10.1002/open.201600048. eCollection 2016 Aug.
The syntheses of the phosphonyl-substituted ferrocenyl stannane Fe[{η (5)-C5H3-1-SnPh3-2-P(O)(O-iPr)2}{η (5)-C5H4P(O)(O-iPr)2}] (1) and its iodine derivative Fe[{η (5)-C5H3-1-SnPh2I-2-P(O)(O-iPr)2}{η (5)-C5H4P(O)(O-iPr)2}] (2) are reported. The syntheses of the corresponding salts Fe[{η (5)-C5H3-1-SnPh2-2-P(O)(O-iPr)2}{η (5)-C5H4P(O)(O-iPr)2}]X (3, X=Al{OC(CF3)3}4, 4, X=ClO4, 5, X=HgI3), respectively, are also described. The compounds are characterized by elemental analyses, (1)H, (13)C, (31)P, (119)Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and, except for 4 and 5, single-crystal X-ray diffraction analyses.
报道了膦酰基取代的二茂铁基锡烷Fe[{η(5)-C5H3-1-SnPh3-2-P(O)(O-iPr)2}{η(5)-C5H4P(O)(O-iPr)2}]（1）及其碘衍生物Fe[{η(5)-C5H3-1-SnPh2I-2-P(O)(O-iPr)2}{η(5)-C5H4P(O)(O-iPr)2}]（2）的合成。还分别描述了相应盐Fe[{η(5)-C5H3-1-SnPh2-2-P(O)(O-iPr)2}{η(5)-C5H4P(O)(O-iPr)2}]X（3，X = Al{OC(CF3)3}4；4，X = ClO4；5，X = HgI3）的合成。通过元素分析、1H、13C、31P、119Sn核磁共振和红外光谱、电喷雾电离质谱对这些化合物进行了表征，除了4和5之外，还进行了单晶X射线衍射分析。
