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由二噻吩并[3,2-b:2',3'-d]吡咯并[3,4-c]吡咯-1,4-二酮功能化富勒烯组成的有机二聚体用于单组分高效有机太阳能电池。

An Organic Dyad Composed of Diathiafulvalene-Functionalized Diketopyrrolopyrrole-Fullerene for Single-Component High-Efficiency Organic Solar Cells.

机构信息

Inorganic & Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Tarnaka, Hyderabad-, 500007, India.

Network Institute of Solar Energy (CSIR-NISE) and Academy of Scientific and Innovative Research (AcSIR), New Delhi, India.

出版信息

Angew Chem Int Ed Engl. 2016 Sep 26;55(40):12334-7. doi: 10.1002/anie.201602969. Epub 2016 Aug 30.

Abstract

A new low-band gap dyad DPP-Ful, which consists of covalently linked dithiafulvalene-functionalized diketopyrrolopyrrole as donor and fullerene (C60 ) as the acceptor, has been designed and synthesized. Organic solar cells were successfully constructed using the DPP-Ful dyad as an active layer. This system has a record power-conversion efficiency (PCE) of 2.2 %, which is the highest value when compared to reported single-component organic solar cells.

摘要

一个新的低带隙二聚体 DPP-Ful,由共价连接的二噻吩并富勒烯官能化二酮吡咯并吡咯作为供体和富勒烯(C60)作为受体组成,已经被设计和合成。使用 DPP-Ful 二聚体作为活性层成功构建了有机太阳能电池。该系统具有创纪录的功率转换效率(PCE)为 2.2%,与报道的单一组分有机太阳能电池相比,这是最高的值。

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