School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Carbohydr Polym. 2016 Dec 10;154:13-9. doi: 10.1016/j.carbpol.2016.08.030. Epub 2016 Aug 10.
The oxidized amyloses with different carboxyl content were prepared to include linalool for antimicrobial activity in aqueous environment. The results show that linalool can be effectively reserved from volatilization through encapsulation into amylose and oxidized amyloses. The inclusion ability of oxidized amyloses towards linalool is decreasing with the increase of oxidation level due to the depolymerization of amylose. However, the solubilization effect of oxidized amyloses to linalool is enhanced efficiently owning to the high water solubility of oxidized amyloses. It is interesting that the inclusion complexes have good antimicrobial activity in aqueous environment. Linalool solubilized by oxidized amyloses presents better antimicrobial performance than that solubilized by amylose, mainly resulting from that amylose-linalool inclusion complex would aggregate and retrograde fast in aqueous solution, which is disadvantageous for the release of linalool. The study suggests that oxidized amylose is a promising solubilizer and carrier of linalool for antimicrobial activity in aqueous environment.
制备了不同羧基含量的氧化淀粉,将其与芳樟醇混合,以提高其在水相环境中的抗菌活性。结果表明,芳樟醇可以通过包埋到直链淀粉和氧化淀粉中而有效地防止挥发。由于直链淀粉的降解,氧化淀粉对芳樟醇的包合能力随着氧化程度的增加而降低。然而,氧化淀粉对芳樟醇的溶解效果得到了有效增强,这是因为氧化淀粉具有较高的水溶性。有趣的是,包合物在水相环境中具有良好的抗菌活性。与直链淀粉相比,氧化淀粉包合的芳樟醇具有更好的抗菌性能,主要是因为直链淀粉-芳樟醇包合物在水溶液中会聚集并快速逆向反应,不利于芳樟醇的释放。研究表明,氧化淀粉是一种很有前途的直链淀粉的增溶剂和芳樟醇载体,可提高其在水相环境中的抗菌活性。