镍催化促进两个杂芳环之间的氧化 C(sp(2) )-H/C(sp(2) )-H 交叉偶联反应。
Nickel Catalysis Enables Oxidative C(sp(2) )-H/C(sp(2) )-H Cross-Coupling Reactions between Two Heteroarenes.
机构信息
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.
出版信息
Angew Chem Int Ed Engl. 2016 Sep 26;55(40):12275-9. doi: 10.1002/anie.201606529. Epub 2016 Sep 6.
Nickel can be used to promote oxidative C(sp(2) )-H/C(sp(2) )-H cross-coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional-group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
镍可以用于促进两个杂芳环之间的氧化 C(sp(2) )-H/C(sp(2) )-H 交叉偶联。该反应的范围可以扩展到芳香酰胺作为偶联伙伴。该反应表现出高的官能团兼容性和广泛的底物范围。银氧化剂可以回收利用，以降低成本和减少浪费，这对实际应用非常有用。
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