血红蛋白的动力学与过渡态理论
Kinetics of hemoglobin and transition state theory.
作者信息
Szabo A
出版信息
Proc Natl Acad Sci U S A. 1978 May;75(5):2108-11. doi: 10.1073/pnas.75.5.2108.
Abstract
Experimental evidence indicates that the way cooperativity in hemoglobin is manifested kinetically depends on the nature of the ligand. It is shown that the qualitative differences in the kinetics of NO, O2, CO, and bulky isocyanides can be understood in structural terms in a framework based on transition state theory.
摘要
实验证据表明，血红蛋白协同性的动力学表现方式取决于配体的性质。研究表明，在基于过渡态理论的框架下，从结构角度可以理解一氧化氮、氧气、一氧化碳和大分子异氰化物在动力学上的定性差异。
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