用于催化应用的有机及有机-无机杂化聚合物载体的研究进展

Advances in Organic and Organic-Inorganic Hybrid Polymeric Supports for Catalytic Applications.

作者信息

Salvo Anna Maria Pia, Giacalone Francesco, Gruttadauria Michelangelo

机构信息

Dipartimento Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF) Università di Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy.

出版信息

Molecules. 2016 Sep 28;21(10):1288. doi: 10.3390/molecules21101288.

DOI:10.3390/molecules21101288

PMID:27689980

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6274031/

Abstract

In this review, the most recent advances (2014-2016) on the synthesis of new polymer-supported catalysts are reported, focusing the attention on the synthetic strategies developed for their preparation. The polymer-supported catalysts examined will be organic-based polymers and organic-inorganic hybrids and will include, among others, polystyrenes, poly-ionic liquids, chiral ionic polymers, dendrimers, carbon nanotubes, as well as silica and halloysite-based catalysts. Selected examples will show the synthesis and application in the field of organocatalysis and metal-based catalysis both for non-asymmetric and asymmetric transformations.

摘要

在本综述中，报道了新型聚合物负载催化剂合成方面的最新进展（2014 - 2016年），重点关注为其制备所开发的合成策略。所研究的聚合物负载催化剂将包括有机基聚合物和有机 - 无机杂化材料，其中包括聚苯乙烯、聚离子液体、手性离子聚合物、树枝状大分子、碳纳米管，以及基于二氧化硅和埃洛石的催化剂。所选实例将展示其在有机催化和金属基催化领域用于非不对称和不对称转化的合成及应用。