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通过设计双 Gemini 型两亲性两性离子及其自组装构建螺旋状结构矩阵。

Construction of gyroid-structured matrices through the design of geminized amphiphilic zwitterions and their self-organization.

作者信息

Matsumoto Takuro, Ono Ayaka, Ichikawa Takahiro, Kato Takashi, Ohno Hiroyuki

机构信息

Department of Biotechnology, Tokyo University of Agriculture and Technology, Nakacho, Koganei, Tokyo 184-8588, Japan.

Department of Chemistry and Biotechnology, The University of Tokyo, Bunkyo-ku, Hongo, Tokyo 113-8656, Japan.

出版信息

Chem Commun (Camb). 2016 Oct 6;52(82):12167-12170. doi: 10.1039/c6cc06840e.

Abstract

Gemini amphiphilic zwitterions exhibit thermotropic bicontinuous cubic liquid-crystalline phases having a 3D continuous ionic domain. Incorporation of an acid into the materials led to the creation of novel electrolytes transporting protons efficiently through the 3D continuous domain.

摘要

Gemini两亲性两性离子呈现出具有三维连续离子域的热致双连续立方液晶相。将酸掺入材料中导致产生了新型电解质,其能够通过三维连续域有效地传输质子。

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