Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University , Chikusa-ku, Nagoya 464-8603, Japan.
Graduate School of Natural Science and Technology, Kanazawa University , Kakuma-machi, Kanazawa 920-1192, Japan.
Chem Rev. 2016 Nov 23;116(22):13752-13990. doi: 10.1021/acs.chemrev.6b00354. Epub 2016 Oct 18.
In this review, we describe the recent advances in supramolecular helical assemblies formed from chiral and achiral small molecules, oligomers (foldamers), and helical and nonhelical polymers from the viewpoints of their formations with unique chiral phenomena, such as amplification of chirality during the dynamic helically assembled processes, properties, and specific functionalities, some of which have not been observed in or achieved by biological systems. In addition, a brief historical overview of the helical assemblies of small molecules and remarkable progress in the synthesis of single-stranded and multistranded helical foldamers and polymers, their properties, structures, and functions, mainly since 2009, will also be described.
在这篇综述中，我们从独特的手性现象的角度描述了由手性和非手性小分子、低聚物（构象聚合物）以及螺旋和非螺旋聚合物形成的超分子螺旋组装体的最新进展，例如在动态螺旋组装过程中手性的放大，以及它们的性质和特定功能，其中一些现象在生物系统中没有观察到或实现。此外，还将简要介绍小分子螺旋组装的历史概况，以及自 2009 年以来在单链和多链螺旋构象聚合物的合成、性质、结构和功能方面的显著进展。
