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水溶性羧酸联苯[4]芳烃的合成及其对乙酰胆碱的选择性络合。

Synthesis of a Water-Soluble Carboxylatobiphen[4]arene and Its Selective Complexation toward Acetylcholine.

机构信息

Department of Chemistry, Center for Supramolecular and Catalytic Chemistry, Shanghai University , Shanghai 200444, P. R. China.

State Key Laboratory of Toxicology and Medical Countermeasures, Beijing Institute of Pharmacology and Toxicology , Beijing 100850, P. R. China.

出版信息

Org Lett. 2016 Nov 4;18(21):5740-5743. doi: 10.1021/acs.orglett.6b03005. Epub 2016 Oct 19.

DOI:10.1021/acs.orglett.6b03005
PMID:27759397
Abstract

The first water-soluble biphen[4]arene containing eight carboxylato moieties (carboxylatobiphen[4]arene, CBP4) has been synthesized. Selective molecular recognition of acetylcholine (ACh) against choline (Ch) and betaine (Bt) and pH-responsive host-guest complexation in aqueous media are described.

摘要

首次合成了一种含有八个羧基官能团的水溶性联苯[4]芳烃（羧基联苯[4]芳烃，CBP4）。描述了其在水相介质中对乙酰胆碱（ACh）与胆碱（Ch）和甜菜碱（Bt）的选择性分子识别以及对 pH 的响应的主客体络合作用。

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