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采用多壁碳纳米管修饰电极电化学检测和定量生姜(Zingiber officinale)中的姜辣素种类。

Electrochemical detection and quantification of gingerol species in ginger (Zingiber officinale) using multiwalled carbon nanotube modified electrodes.

机构信息

Department of Chemistry, Oxford University, Physical & Theoretical Chemistry Laboratory, South Parks Road, Oxford, UK.

出版信息

Analyst. 2016 Oct 24;141(22):6321-6328. doi: 10.1039/c6an02254e.

Abstract

We demonstrate the potential of electrochemical detection for the analysis of the 'strength' of ginger in ginger sample. This facile and fast detection method is aimed at the quality control in food industry. Specifically, we report adsorptive stripping voltammetry (AdsSV) as a technique for detection of gingerol compounds, the pungent components of ginger rhizome. Among the gingerols, 6-gingerol is the most abundant and is chosen as a model to characterise the behaviour of a wider range of related compounds. Multiwalled carbon nanotube modified basal plane pyrolytic graphite electrodes (MWCNT-BPPG electrode) are employed to enhance the sensitivity of the measurement. A linearity range from 1 μM to 50 μM with limit of detection of 0.21 μM and limit of quantification of 0.71 μM is obtained. Further, the simple and rapid extraction procedure by simply vortexing the ginger sample with ethanol is developed for extraction of gingerol related species.

摘要

我们展示了电化学检测在分析生姜样品中“姜辣素”含量的潜力。这种简单快速的检测方法旨在用于食品工业的质量控制。具体而言,我们报告了吸附溶出伏安法(AdsSV)作为一种检测姜辣素化合物的技术,姜辣素化合物是生姜根茎的刺激性成分。在姜辣素中,6-姜辣素是最丰富的,被选为一种模型来描述更广泛的相关化合物的行为。多壁碳纳米管修饰的基底平面热解石墨电极(MWCNT-BPPG 电极)用于提高测量的灵敏度。获得了从 1 μM 到 50 μM 的线性范围,检测限为 0.21 μM,定量限为 0.71 μM。此外,还开发了一种简单快速的提取方法,只需将生姜样品与乙醇涡旋混合即可提取姜辣素相关物质。

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