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通过纳滤和光催化剂氧化处理合成鳟鱼养殖场废水的氟苯尼考。

Treatment of florfenicol of synthetic trout fish farm wastewater through nanofiltration and photocatalyst oxidation.

作者信息

Esmaili Zakie, Cheshmberah Fatemeh, Solaimany Nazar Ali R, Farhadian Mehrdad

机构信息

a Department of Chemical Engineering, Faculty of Engineering , University of Isfahan , Isfahan , Iran.

出版信息

Environ Technol. 2017 Aug;38(16):2040-2047. doi: 10.1080/09593330.2016.1245359. Epub 2016 Oct 24.

Abstract

The aquaculture system is a potential significant source of antibacterial agents. The removal of florfenicol (Flo) antibiotic from synthetic aqueous wastewater is performed by applying a commercial thin film composite polyamide nanofilter (NF). For concentrated wastewater treatment, the advanced oxidation process (AOP) is applied. The effects of pH, pressure and Flo concentration on removal efficiency of NF and the effects of pH, Flo concentration and dosage of hydrogen peroxide and contact time on the AOP are assessed. In the nanofiltration system, it is found that an increase in pH enhances the removal efficiency up to 99%. In this membrane, an increase of pressure between 4 and 7 bar would increase the removal percentage, followed by a decrease from 7 to 10 bar. In AOP, it is observed that the degradation efficiency of Flo increases by both an increase in its initial concentration up to values above 50 ppm and contact time. The degradation efficiency of Flo is at its highest in the pH range of 7-10. With increasing HO dosage, from 0 to 500 ppm, the removal efficiency increases. The results of this study indicate that a combination of a polyamide nanofilteration together with an AOP introduces an effective manner of removing Flo antibiotic from synthetic trout fish farm wastewater.

摘要

水产养殖系统是抗菌剂的一个潜在重要来源。通过应用一种商用的复合聚酰胺纳滤膜(NF)来去除合成废水中的氟苯尼考(Flo)抗生素。对于浓缩废水处理,采用了高级氧化工艺(AOP)。评估了pH值、压力和Flo浓度对NF去除效率的影响,以及pH值、Flo浓度、过氧化氢用量和接触时间对AOP的影响。在纳滤系统中,发现pH值升高可将去除效率提高至99%。在这种膜中,压力在4至7巴之间增加会提高去除率,随后从7至10巴则会下降。在AOP中,观察到Flo的降解效率会随着其初始浓度增加至50 ppm以上以及接触时间的增加而提高。Flo的降解效率在pH值为7至10的范围内最高。随着过氧化氢用量从0增加到500 ppm,去除效率提高。本研究结果表明,聚酰胺纳滤与AOP相结合为从合成鳟鱼养殖场废水中去除Flo抗生素提供了一种有效方法。

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