负载于介孔碳上的二氧化铈纳米棒作为亚胺合成的高效催化剂。
CeO nanorods anchored on mesoporous carbon as an efficient catalyst for imine synthesis.
作者信息
Geng Longlong, Song Jinling, Zhou Yahui, Xie Yan, Huang Jiahui, Zhang Wenxiang, Peng Luming, Liu Gang
机构信息
Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun, 130012, China.
Key Laboratory of Mesoscopic Chemistry of Ministry of Education and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Chem Commun (Camb). 2016 Nov 10;52(92):13495-13498. doi: 10.1039/c6cc05496j.
CeO nanorods anchored on mesoporous carbon exhibit high activity and stability in aerobic oxidative coupling of alcohols and amines to imines. The abundant surface Ce and the suitable interaction between CeO nanorods and the carbon support should be responsible for the excellent catalytic behaviors.
锚定在介孔碳上的CeO纳米棒在醇和胺有氧氧化偶联生成亚胺的反应中表现出高活性和稳定性。丰富的表面Ce以及CeO纳米棒与碳载体之间合适的相互作用应是优异催化性能的原因。
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