源自维生素B12的介孔碳：一种用于亚胺形成的高性能双功能催化剂。
Mesoporous carbon derived from vitamin B12: a high-performance bifunctional catalyst for imine formation.
作者信息
Chen Bo, Shang Sensen, Wang Lianyue, Zhang Yi, Gao Shuang
机构信息
Dalian National Laboratory for Clean Energy (DNL), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, China.
出版信息
Chem Commun (Camb). 2016 Jan 11;52(3):481-4. doi: 10.1039/c5cc06179b. Epub 2015 Nov 3.
PMID:26529323
Abstract
Mesoporous carbon derived from natural vitamin B12 is applied for the first time in organic synthesis and exhibits exceptionally high dual activity for imine formation via the cross-coupling of alcohols with amines and the self-coupling of primary amines using molecular oxygen or air as the terminal oxidant.
摘要
源自天然维生素B12的介孔碳首次应用于有机合成，并通过醇与胺的交叉偶联以及使用分子氧或空气作为终端氧化剂的伯胺自偶联，对亚胺形成表现出极高的双重活性。
Zotero 插件