Lu Chuan-Jun, Chen Hong, Chen Dong-Kai, Wang Hong, Yang Zhen-Ping, Gao Jianrong, Jin Hongwei
College of Chemical Engineering, Zhejiang University of Technology, Chaowang Road 18#, Hangzhou 310014, China.
Org Biomol Chem. 2016 Nov 22;14(46):10833-10839. doi: 10.1039/c6ob01929c.
A novel method for the construction of allyl arylsulfone derivatives was developed by palladium catalyzed allylation of sulfonyl hydrazides with alkynes. A series of structurally diverse allyl arylsulfones can be regioselectively synthesized in high yields under mild conditions.
通过钯催化磺酰肼与炔烃的烯丙基化反应,开发了一种构建烯丙基芳基砜衍生物的新方法。在温和条件下,可以高产率区域选择性地合成一系列结构多样的烯丙基芳基砜。