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Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis.
Angew Chem Int Ed Engl. 2017 Sep 11;56(38):11312-11325. doi: 10.1002/anie.201704248. Epub 2017 Aug 10.
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Transition metal-carboryne complexes: synthesis, bonding, and reactivity.
Acc Chem Res. 2011 Apr 19;44(4):299-309. doi: 10.1021/ar100156f. Epub 2011 Mar 11.
5
More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions.
Angew Chem Int Ed Engl. 2008;47(5):840-71. doi: 10.1002/anie.200700278.
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Group 11 metal amide-catalyzed asymmetric cycloaddition reactions of azomethine imines with terminal alkynes.
J Am Chem Soc. 2012 Dec 12;134(49):20049-52. doi: 10.1021/ja311150n. Epub 2012 Dec 4.
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Consecutive intermolecular reductive hydroamination: cooperative transition-metal and chiral Brønsted acid catalysis.
Chemistry. 2012 Jul 16;18(29):9005-10. doi: 10.1002/chem.201200109. Epub 2012 Jun 15.
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Transition-metal-catalyzed synthesis of aspergillide B: an alkyne addition strategy.
Org Lett. 2012 Mar 2;14(5):1322-5. doi: 10.1021/ol300200m. Epub 2012 Feb 22.

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3
Catalytic Enantioselective C-C Coupling of Alcohols for Polyketide Total Synthesis beyond Chiral Auxiliaries and Premetalated Reagents.
Chem Rev. 2024 Dec 25;124(24):13715-13735. doi: 10.1021/acs.chemrev.4c00858. Epub 2024 Dec 6.
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Nickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes.
Nat Commun. 2023 Nov 22;14(1):7640. doi: 10.1038/s41467-023-43197-z.
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Mechanistic Versatility at Ir(PSiP) Pincer Catalysts: Triflate Proton Shuttling from 2-Butyne to Diene and [3]Dendralene Motifs.
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10
Recent advances in transition metal-free catalytic hydroelementation (E = B, Si, Ge, and Sn) of alkynes.
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1
Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes.
J Am Chem Soc. 2017 Feb 8;139(5):1774-1777. doi: 10.1021/jacs.6b12307. Epub 2017 Jan 27.
2
Stereodivergent Coupling of Aldehydes and Alkynes via Synergistic Catalysis Using Rh and Jacobsen's Amine.
J Am Chem Soc. 2017 Jan 25;139(3):1029-1032. doi: 10.1021/jacs.6b10680. Epub 2017 Jan 11.
3
Palladium-catalyzed allylation of sulfonyl hydrazides with alkynes to synthesize allylic arylsulfones.
Org Biomol Chem. 2016 Nov 22;14(46):10833-10839. doi: 10.1039/c6ob01929c.
4
The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies.
Chemistry. 2017 Jan 12;23(3):541-545. doi: 10.1002/chem.201605011. Epub 2016 Dec 1.
6
Cooperative Palladium/Proline-Catalyzed Direct α-Allylic Alkylation of Ketones with Alkynes.
Org Lett. 2016 Oct 21;18(20):5332-5335. doi: 10.1021/acs.orglett.6b02649. Epub 2016 Sep 29.
8
Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes.
Acc Chem Res. 2016 Aug 16;49(8):1524-36. doi: 10.1021/acs.accounts.6b00252. Epub 2016 Jul 25.
9
Palladium-Catalyzed Dearomative Allylic Alkylation of Indoles with Alkynes To Synthesize Indolenines with C3-Quarternary Centers.
Org Lett. 2016 Aug 5;18(15):3906-9. doi: 10.1021/acs.orglett.6b01947. Epub 2016 Jul 21.
10
Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers.
Angew Chem Int Ed Engl. 2016 Jul 11;55(29):8440-3. doi: 10.1002/anie.201603538. Epub 2016 May 31.

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