Zhang Yiteng, Wirthwein Aaron, Alharbi Fahhad H, Engel Gregory S, Kais Sabre
Department of Physics, Purdue University, West Lafayette, IN 47907, USA.
Department of Physics, Wabash College, Crawfordsville, IN 47933, USA.
Phys Chem Chem Phys. 2016 Nov 23;18(46):31845-31849. doi: 10.1039/c6cp06098f.
The high efficiency of the photon-to-charge conversion process found in photosynthetic complexes has inspired researchers to explore a new route for designing artificial photovoltaic materials. Quantum coherence can provide a mean to surpass the Shockley-Quiesser device concept limit by reducing the radiative recombination. Taking inspiration from these new discoveries, we consider a linearly-aligned system as a light-harvesting antennae composed of two-level optical emitters coupled with each other by dipole-dipole interactions. Our simulations show that the certain dark states can enhance the power with the aid of intra-band phononic dissipation. Due to cooperative effects, the output power will be improved when incorporating more emitters in the linear system.
光合复合物中发现的高效光子到电荷的转换过程激发了研究人员探索设计人工光伏材料的新途径。量子相干可以通过减少辐射复合提供一种超越肖克利-奎塞尔器件概念极限的方法。受这些新发现的启发,我们将一个线性排列系统视为由通过偶极-偶极相互作用相互耦合的二能级光学发射器组成的光收集天线。我们的模拟表明,某些暗态可以借助带内声子耗散来提高功率。由于协同效应,在线性系统中加入更多发射器时输出功率会得到提高。