Vial Laurent, Dumartin Melissa, Donnier-Maréchal Marion, Perret Florent, Francoia Jean-Patrick, Leclaire Julien
Institut des Biomolécules Max Mousseron, UMR 5247 CNRS - Université de Montpellier - ENSCM, Place Eugène Bataillon, 34296 Montpellier cedex 5, France.
Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR 5246 CNRS - Université Claude Bernard Lyon 1 - CPE Lyon - INSA, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne cedex, France.
Chem Commun (Camb). 2016 Dec 6;52(99):14219-14221. doi: 10.1039/c6cc07713g.
The asymmetric deformation of a dyn[4]arene upon the binding of various lysine derivatives leads to distinct induced circular dichroism outputs in buffered water, which can be exploited not only for the determination of their enantiomeric excesses, but also for their classification by linear discriminant analysis.
当各种赖氨酸衍生物结合时，[4]芳烃大环的不对称变形会在缓冲水中产生不同的诱导圆二色性输出，这不仅可用于测定它们的对映体过量，还可通过线性判别分析对它们进行分类。
