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具有微平行流场的质子交换膜(PEM)燃料电池的三维传输建模

Three-Dimensional Transport Modeling for Proton Exchange Membrane(PEM) Fuel Cell with Micro Parallel Flow Field.

作者信息

Lee Pil Hyong, Han Sang Seok, Hwang Sang Soon

机构信息

Department of Mechanical Engineering, University of Incheon, 177 Dohwa -Dong , Nam-Gu, Incheon, Korea.

出版信息

Sensors (Basel). 2008 Mar 3;8(3):1475-1487. doi: 10.3390/s8031475.

Abstract

Modeling and simulation for heat and mass transport in micro channel are beingused extensively in researches and industrial applications to gain better understanding of thefundamental processes and to optimize fuel cell designs before building a prototype forengineering application. In this study, we used a single-phase, fully three dimensionalsimulation model for PEMFC that can deal with both anode and cathode flow field forexamining the micro flow channel with electrochemical reaction. The results show thathydrogen and oxygen were solely supplied to the membrane by diffusion mechanism ratherthan convection transport, and the higher pressure drop at cathode side is thought to becaused by higher flow rate of oxygen at cathode. And it is found that the amount of water incathode channel was determined by water formation due to electrochemical reaction pluselectro-osmotic mass flux directing toward the cathode side. And it is very important tomodel the back diffusion and electro-osmotic mass flux accurately since the two flux wasclosely correlated each other and greatly influenced for determination of ionic conductivityof the membrane which directly affects the performance of fuel cell.

摘要

微通道内传热传质的建模与仿真在研究和工业应用中得到了广泛应用,以便更好地理解基本过程,并在构建工程应用原型之前优化燃料电池设计。在本研究中,我们使用了一个用于质子交换膜燃料电池(PEMFC)的单相、全三维仿真模型,该模型可以处理阳极和阴极流场,以研究存在电化学反应的微流道。结果表明,氢气和氧气仅通过扩散机制而非对流传输供应至膜,并且认为阴极侧较高的压降是由阴极处较高的氧气流速引起的。并且发现阴极通道中的水量由电化学反应产生的水以及指向阴极侧的电渗质量通量决定。准确模拟反向扩散和电渗质量通量非常重要,因为这两种通量相互密切相关,并且对膜离子电导率的测定有很大影响,而膜离子电导率直接影响燃料电池的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7ff4/3663005/d963b12b6744/sensors-08-01475f1.jpg

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