Ma Jianqing, Yang Qunfeng, Xu Dongmei, Zeng Xiaomei, Wen Yuezhong, Liu Weiping
MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou, 310058, China.
College of Biological and Environmental Engineering, Zhejiang Shuren University, Hangzhou, 310015, China.
Environ Sci Pollut Res Int. 2017 Feb;24(4):3820-3828. doi: 10.1007/s11356-016-8114-y. Epub 2016 Nov 29.
Powdered activated carbons (PACs) with micrometer size are showing great potential for enabling and improving technologies in water treatment. The critical problem in achieving practical application of PAC involves simple, effective fabrication of magnetic PAC and the design of a feasible reactor that can remove pollutants and recover the adsorbent efficiently. Herein, we show that such materials can be fabricated by the combination of PAC and magnetic FeO with chitosan-Fe hydrogel through a simple co-precipitation method. According to the characterization results, CS-Fe/FeO/PAC with different micrometers in size exhibited excellent magnetic properties. The adsorption of tetracycline was fast and efficient, and 99.9% removal was achieved in 30 min. It also possesses good usability and stability to co-existing ions, organics, and different pH values due to its dispersive interaction nature. Finally, the prepared CS-Fe/FeO/PAC also performed well in the fluidized bed reactor with electromagnetic separation function. It could be easily separated by applying a magnetic field and was effectively in situ regenerated, indicating a potential of practical application for the removal of pollutants from water.
微米级的粉末活性炭(PACs)在实现和改进水处理技术方面显示出巨大潜力。实现PAC实际应用的关键问题包括简单、有效地制备磁性PAC以及设计一种可行的反应器,该反应器能够有效去除污染物并回收吸附剂。在此,我们表明,通过简单的共沉淀法,将PAC与磁性FeO与壳聚糖-铁水凝胶相结合,可以制备出此类材料。根据表征结果,不同微米尺寸的CS-Fe/FeO/PAC表现出优异的磁性。对四环素的吸附快速高效,30分钟内去除率达到99.9%。由于其分散相互作用性质,它对共存离子、有机物和不同pH值也具有良好的可用性和稳定性。最后,制备的CS-Fe/FeO/PAC在具有电磁分离功能的流化床反应器中也表现良好。通过施加磁场可以很容易地将其分离,并且能够有效地原位再生,这表明其在从水中去除污染物方面具有实际应用潜力。