Lin Xu, Kurata Hiroki, Prabhu Deepak D, Yamauchi Mitsuaki, Ohba Tomonori, Yagai Shiki
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
Department of Chemistry, Graduate School of Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
Chem Commun (Camb). 2016 Dec 20;53(1):168-171. doi: 10.1039/c6cc08995j.
An alkylene-tethered perylene bisimide (PBI) dyad with hydrophilic substituents forms helical supramolecular polymers that can be visualized by AFM in THF-water mixtures. The supramolecular polymers also form thixotropic gel-like lyotropic mesophases in the mixtures.
一种带有亲水性取代基的亚烷基连接的苝二酰亚胺(PBI)二元体形成螺旋超分子聚合物,可通过原子力显微镜(AFM)在四氢呋喃 - 水混合物中观察到。这些超分子聚合物在混合物中还形成触变性凝胶状溶致液晶相。