Darses B, Rodrigues R, Neuville L, Mazurais M, Dauban P
Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Univ. Paris-Sud, Université Paris-Saclay, 1, av. de la Terrasse, 91198 Gif-sur-Yvette, France.
Chem Commun (Camb). 2017 Jan 3;53(3):493-508. doi: 10.1039/c6cc07925c.
The significant progress made in the area of transition metal-catalyzed nitrene transfer into C-H or C[double bond, length as m-dash]C bonds mediated by iodine(iii) oxidants has been translated into many elegant synthetic applications. This feature article summarizes the main total syntheses that take advantage of such reactions, thereby highlighting that catalytic C(sp)-H amination and alkene aziridination reactions have carved out their place in the organic chemist's toolbox.
在过渡金属催化的氮宾转移到由碘（III）氧化剂介导的C-H或C=C键领域所取得的重大进展，已转化为许多出色的合成应用。这篇专题文章总结了利用此类反应的主要全合成，从而突出了催化C(sp)-H胺化反应和烯烃氮杂环丙烷化反应在有机化学家的工具库中已占有一席之地。
