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空气稳定的铜基P2-NaCuFeMnO作为一种新型钠离子电池正极材料

Air-Stable Copper-Based P2-NaCuFeMnO as a New Positive Electrode Material for Sodium-Ion Batteries.

作者信息

Li Yunming, Yang Zhenzhong, Xu Shuyin, Mu Linqin, Gu Lin, Hu Yong-Sheng, Li Hong, Chen Liquan

机构信息

Key Laboratory for Renewable Energy Beijing Key Laboratory for New Energy Materials and Devices Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China.

Laboratory for Advanced Materials and Electron Microscopy Institute of Physics Chinese Academy of Sciences Beijing 100190 China.

出版信息

Adv Sci (Weinh). 2015 May 4;2(6):1500031. doi: 10.1002/advs.201500031. eCollection 2015 Jun.

DOI:10.1002/advs.201500031
PMID:27980950
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5115408/
Abstract

is designed and synthesized by a simple solid-state method and investigated as a positive electrode material for sodium-ion batteries. The attractive long cycling stability is demonstrated by the capacity retention of 85% after 150 cycles at 1 C rate without phase transformation. The reversible Cu/Cu redox couple in P2 phase oxides is proved for the first time.

摘要

通过简单的固态方法设计并合成,并作为钠离子电池的正极材料进行研究。在1 C倍率下循环150次后容量保持率为85%,且无相转变,证明了其具有吸引人的长循环稳定性。首次证明了P2相氧化物中可逆的Cu/Cu氧化还原对。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/b49a7782ec32/ADVS-2-0b-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/dc7053489f53/ADVS-2-0b-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/66df9e394162/ADVS-2-0b-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/02f544a0a6a4/ADVS-2-0b-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/5e4d41f3da75/ADVS-2-0b-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/b49a7782ec32/ADVS-2-0b-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/dc7053489f53/ADVS-2-0b-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/66df9e394162/ADVS-2-0b-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/02f544a0a6a4/ADVS-2-0b-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/5e4d41f3da75/ADVS-2-0b-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df4/5115408/b49a7782ec32/ADVS-2-0b-g006.jpg

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