Wu Hongzhuo, Fang Renren, Tao Jingwei, Wang Deliang, Qiao Xiaolan, Yang Xiaodi, Hartl František, Li Hongxiang
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China.
Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.
Chem Commun (Camb). 2017 Jan 5;53(4):751-754. doi: 10.1039/c6cc09184a.
We herein report on an efficient synthesis of diacenaphthylene-fused benzo[1,2-b:4,5-b']dithiophenes and demonstrate that their packing structure in the solid state depends on the substituent groups. These compounds form dimers with their radical cations in high concentration solution and exhibit good field-effect mobility.
我们在此报告二萘嵌苯稠合苯并[1,2-b:4,5-b']二噻吩的高效合成,并证明它们在固态下的堆积结构取决于取代基。这些化合物在高浓度溶液中与它们的自由基阳离子形成二聚体,并表现出良好的场效应迁移率。