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二萘嵌苯并稠合苯并[1,2 - b:4,5 - b']二噻吩:含有全碳五元芳香环的多环杂并苯

Diacenaphthylene-fused benzo[1,2-b:4,5-b']dithiophenes: polycyclic heteroacenes containing full-carbon five-membered aromatic rings.

作者信息

Wu Hongzhuo, Fang Renren, Tao Jingwei, Wang Deliang, Qiao Xiaolan, Yang Xiaodi, Hartl František, Li Hongxiang

机构信息

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China.

Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.

出版信息

Chem Commun (Camb). 2017 Jan 5;53(4):751-754. doi: 10.1039/c6cc09184a.

DOI:10.1039/c6cc09184a
PMID:27995232
Abstract

We herein report on an efficient synthesis of diacenaphthylene-fused benzo[1,2-b:4,5-b']dithiophenes and demonstrate that their packing structure in the solid state depends on the substituent groups. These compounds form dimers with their radical cations in high concentration solution and exhibit good field-effect mobility.

摘要

我们在此报告二萘嵌苯稠合苯并[1,2-b:4,5-b']二噻吩的高效合成,并证明它们在固态下的堆积结构取决于取代基。这些化合物在高浓度溶液中与它们的自由基阳离子形成二聚体,并表现出良好的场效应迁移率。

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