钯/铜协同催化二苯胺的氧化 C-H/C-H 羰基化反应：一种获得吖啶酮的方法。
Palladium/Copper Co-catalyzed Oxidative C-H/C-H Carbonylation of Diphenylamines: A Way To Access Acridones.
机构信息
The Institute for Advanced Studies (IAS), College of Chemistry and Molecular Sciences, Wuhan University , Wuhan 430072, Hubei, China.
Conducted and State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , Lanzhou 730000, China.
出版信息
Org Lett. 2017 Jan 6;19(1):94-97. doi: 10.1021/acs.orglett.6b03356. Epub 2016 Dec 20.
An efficient palladium/copper co-catalyzed oxidative double C(sp)-H functionalization/carbonylation of diphenylamines for synthesis of acridones has been developed. This method utilizes readily available starting materials and mild reaction conditions. The protocol provides a simple, efficient, and atom-economic way to access acridones. Notably, the present protocol has excellent functional group tolerance and application value.
一种高效的钯/铜协同催化氧化双 C(sp)-H 官能化/羰基化二苯胺合成吖啶酮的方法已经被开发出来。该方法利用易得的起始原料和温和的反应条件。该方案提供了一种简单、高效和原子经济性的方法来获得吖啶酮。值得注意的是，本方案具有优异的官能团耐受性和应用价值。
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