自组装分子阶梯和梯子中的双功能路易斯酸性间隔基
A Bifunctional Lewis Acidic Spacer in Self-Assembled Molecular Stairs and Ladders.
作者信息
Gabbaï François P, Schier Annette, Riede Jürgen
机构信息
Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany), Fax: (+49) 89-2891-3125.
出版信息
Angew Chem Int Ed Engl. 1998 Mar 16;37(5):622-624. doi: 10.1002/(SICI)1521-3773(19980316)37:5<622::AID-ANIE622>3.0.CO;2-G.
Abstract
Depending on the stoichiometry, diindacycle 1 and pyrazine in THF reversibly form a stair- or a ladderlike self-organized coordination polymer. In both cases, the building blocks are assembled at angles close to 90°.
摘要
根据化学计量比，二茚环1和吡嗪在四氢呋喃中可逆地形成阶梯状或梯状自组装配位聚合物。在这两种情况下，结构单元以接近90°的角度组装。
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