Yin Ping, Mitchell Lauren A, Parrish Damon A, Shreeve Jean'ne M
Department of Chemistry, University of Idaho, Moscow, ID, 83844-2343, USA), Fax: (+1) 208-885-9146.
Department of Chemistry, University of Minnesota, Minneapolis, MN, 55455, United States.
Chem Asian J. 2017 Feb 1;12(3):378-384. doi: 10.1002/asia.201601615. Epub 2017 Jan 9.
In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11-13 exhibit favorable overall performance as energetic materials.
在先进含能材料的设计中，高密度爆炸基团因其显著提高密度和分子稳定性而发挥着关键作用。通过多样化的功能化策略，一项涉及各种硝基吡唑阴离子的对比研究表明，这些阴离子在决定性能和稳定性方面至关重要。合成了一系列有前景的吡唑基含能离子衍生物，并通过核磁共振光谱、红外光谱和元素分析对其进行了表征。其中，7、8、11 - 13作为含能材料表现出良好的综合性能。
