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合成月桂酸、绣球酸及其类似物的重要基石。

Valuable building block for the synthesis of lunularic acid, hydrangeic acid and their analogues.

作者信息

Mukkamala Ramesh, Hossain Asik, Singh Aidhen Indrapal

机构信息

a Department of Chemistry , Indian Institute of Technology Madras , Chennai , India.

出版信息

Nat Prod Res. 2017 May;31(9):1085-1090. doi: 10.1080/14786419.2016.1274891. Epub 2017 Jan 3.

DOI:10.1080/14786419.2016.1274891
PMID:28044457
Abstract

A new functionalised sulphone-based building block has been synthesised that enabled C-C bond formation through Julia olefination. The utility of developed building block was demonstrated by successful synthesis of two natural products lunularic acid, hydrangeic acid and initial libraries of their analogues.

摘要

已经合成了一种新型的基于砜的功能化结构单元，该结构单元能够通过朱利亚烯烃化反应形成碳-碳键。通过成功合成两种天然产物月桂酸、绣球酸及其类似物的初始库，证明了所开发结构单元的实用性。

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