Monguchi Yasunari, Ichikawa Tomohiro, Sajiki Hironao
Gifu Pharmaceutical University.
Chem Pharm Bull (Tokyo). 2017;65(1):2-9. doi: 10.1248/cpb.c16-00153.
This paper describes practical and selective hydrogenation methodologies using heterogeneous palladium catalysts. Chemoselectivity develops dependent on the catalyst activity based on the characteristic of the supports, derived from structural components, functional groups, and/or morphologies. We especially focus on our recent development of heterogeneous palladium catalysts supported on chelate resin, ceramic, and spherically shaped activated carbon. In addition, the application of flow technology for chemoselective hydrogenation using the palladium catalysts immobilized on molecular sieves 3A and boron nitride is outlined.
本文描述了使用多相钯催化剂的实用且具有选择性的氢化方法。化学选择性的发展取决于基于载体特性的催化剂活性，这些特性源自结构成分、官能团和/或形态。我们特别关注我们最近开发的负载在螯合树脂、陶瓷和球形活性炭上的多相钯催化剂。此外，还概述了流动技术在使用固定在3A分子筛和氮化硼上的钯催化剂进行化学选择性氢化中的应用。
