Broman Søren Lindbæk, Andersen Cecilie Lindholm, Jousselin-Oba Tanguy, Mansø Mads, Hammerich Ole, Frigoli Michel, Nielsen Mogens Brøndsted
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark.
UMR CNRS 8180, UVSQ, Institut Lavoisier de Versailles, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.
Org Biomol Chem. 2017 Jan 25;15(4):807-811. doi: 10.1039/c6ob02666d.
Two tetraceno[2,1,12,11-opqra]tetracene-extended tetrathia-fulvalenes were prepared and found to undergo reversible conversion into their planar polycyclic aromatic hydrocarbons (PAHs) upon electrochemical oxidation - at potentials probing the best valence bond representations.
制备了两种并四苯[2,1,12,11-opqra]并四苯扩展的四硫富瓦烯,发现在电化学氧化时,在探测最佳价键表示的电位下,它们会可逆地转化为其平面多环芳烃(PAHs)。