N-冠烯：合成与固态性质。
N-Acenoacenes: Synthesis and Solid-State Properties.
机构信息
Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Centre for Advanced Materials (CAM), Im Neuenheimer Feld 225, 69120, Heidelberg, Germany.
出版信息
Chemistry. 2022 Dec 9;28(69):e202201916. doi: 10.1002/chem.202201916. Epub 2022 Oct 25.
Four N-acenoacenes were synthesized and analyzed for their optoelectronic properties and solid-state packings. Two of the regioisomeric acridinoacridines are TIPS-ethynylated, whereas the other pair are Boc- and triflate substituted derivatives. The two TIPS-ethynyldiazaacenoacenes were processed into organic thin-film transistors with saturation hole mobilities reaching 2.9×10 cm (Vs) .
四种 N-杂并苯并菲被合成并分析了它们的光电性质和固态堆积。两个区域异构的吖啶吖啶是 TIPS-乙炔基化的，而另一对是 Boc-和三氟甲磺酸酯取代的衍生物。两个 TIPS-乙炔基二氮杂并苯并菲被加工成有机薄膜晶体管，饱和空穴迁移率达到 2.9×10 cm (Vs) 。
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