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N-冠烯：合成与固态性质。

N-Acenoacenes: Synthesis and Solid-State Properties.

机构信息

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.

Centre for Advanced Materials (CAM), Im Neuenheimer Feld 225, 69120, Heidelberg, Germany.

出版信息

Chemistry. 2022 Dec 9;28(69):e202201916. doi: 10.1002/chem.202201916. Epub 2022 Oct 25.

DOI:10.1002/chem.202201916
PMID:35947374
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10091707/
Abstract

Four N-acenoacenes were synthesized and analyzed for their optoelectronic properties and solid-state packings. Two of the regioisomeric acridinoacridines are TIPS-ethynylated, whereas the other pair are Boc- and triflate substituted derivatives. The two TIPS-ethynyldiazaacenoacenes were processed into organic thin-film transistors with saturation hole mobilities reaching 2.9×10  cm (Vs) .

摘要

四种 N-杂并苯并菲被合成并分析了它们的光电性质和固态堆积。两个区域异构的吖啶吖啶是 TIPS-乙炔基化的，而另一对是 Boc-和三氟甲磺酸酯取代的衍生物。两个 TIPS-乙炔基二氮杂并苯并菲被加工成有机薄膜晶体管，饱和空穴迁移率达到 2.9×10  cm (Vs) 。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/833464d0f3d8/CHEM-28-0-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/29148b64bfc2/CHEM-28-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/627203c8a8af/CHEM-28-0-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/afae1a6897ed/CHEM-28-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/bf5ee4682a60/CHEM-28-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/5f184e034b4b/CHEM-28-0-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/833464d0f3d8/CHEM-28-0-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/29148b64bfc2/CHEM-28-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/627203c8a8af/CHEM-28-0-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/afae1a6897ed/CHEM-28-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/bf5ee4682a60/CHEM-28-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/5f184e034b4b/CHEM-28-0-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52bc/10091707/833464d0f3d8/CHEM-28-0-g005.jpg

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本文引用的文献

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J Org Chem. 2022 Mar 18;87(6):4124-4133. doi: 10.1021/acs.joc.1c02918. Epub 2022 Mar 7.
2
Synthesis, Aromaticity, and Application of peri-Pentacenopentacene: Localized Representation of Benzenoid Aromatic Compounds.并五苯并五苯的合成、芳香性及应用：苯型芳香化合物的定域表示
Angew Chem Int Ed Engl. 2022 Jan 3;61(1):e202112794. doi: 10.1002/anie.202112794. Epub 2021 Nov 22.
3
Azaacenes Based Electroactive Materials: Preparation, Structure, Electrochemistry, Spectroscopy and Applications-A Critical Review.
基于氮杂蒽的电活性材料：制备、结构、电化学、光谱学及应用——综述
Materials (Basel). 2021 Sep 8;14(18):5155. doi: 10.3390/ma14185155.
4
TIPS-Ethynylated Naphthodiquinoline and Naphthodiacridine: Novel Diazabisacenes.TIPS-乙氧基萘并二醌和萘并二氮杂菲：新型二氮杂并薁。
Chemistry. 2021 Jul 21;27(41):10569-10573. doi: 10.1002/chem.202101246. Epub 2021 May 27.
5
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Chemistry. 2021 Mar 8;27(14):4553-4556. doi: 10.1002/chem.202004761. Epub 2021 Feb 17.
6
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J Org Chem. 2020 Jul 17;85(14):9281-9289. doi: 10.1021/acs.joc.0c01300. Epub 2020 Jul 5.
7
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Acc Chem Res. 2019 Jun 18;52(6):1575-1587. doi: 10.1021/acs.accounts.9b00160. Epub 2019 Jun 6.
10
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J Am Chem Soc. 2019 Jun 12;141(23):9373-9381. doi: 10.1021/jacs.9b03488. Epub 2019 Jun 3.