Zabaleta Imanol, Marchetti Paola, Lohri Christian Riuji, Zurbrügg Christian
a Department of Sanitation, Water and Solid Waste for Development (Sandec) , Eawag: Swiss Federal Institute of Aquatic Science and Technology , Dübendorf , Switzerland.
b Facoltà di Ingegneria - Dipartimento di Ingegneria Civile ed Architettura , Università degli studi di Pavia , Pavia , Italy.
Environ Technol. 2017 Nov;38(22):2856-2865. doi: 10.1080/09593330.2017.1280538. Epub 2017 Jan 23.
Hydrothermal carbonization is a thermochemical process that converts wet organic matter into a sterile, high-calorific solid material called hydrochar. This technology is considered an interesting option for low- and middle-income urban settings, often lacking adequate services and high fraction of wet organic waste. The aim of this study was to study the influence of the loading rate (total solid content) and the maximum temperature reached on the resulting energy ratio (ER) of the process and the fuel properties of the obtained hydrochar. Ten experiments were carried out with a standardized biowaste-feedstock. Different solid contents (2.54%, 4.93%, 7.44%, 9.45%, 12.83%, 15.2% by weight) and different targeted maximum temperatures (170°C, 180°C, 190°C, 200°C) were tested. Compared to the feedstock, all resulting hydrochars had an increased higher heating value (HHV) (average of 29.2 MJ/kg) and carbon content (average of 66.9%) than the original biowaste (19.3 MJ/kg and 46.2%, respectively). The HHV obtained were similar to those of charcoal (29.6 MJ/kg). Higher solid contents resulted in higher hydrochar yields and carbon efficiencies, whereas higher temperatures resulted in higher carbon content and HHV of the hydrochar. The experiment with the highest solid content (15.2%) achieved an ER > 1.
水热碳化是一种热化学过程,可将湿有机物质转化为一种名为水炭的无菌、高热量固体材料。对于往往缺乏足够服务且湿有机废物占比高的中低收入城市地区而言,这项技术被视为一个有吸引力的选择。本研究的目的是研究装载率(总固体含量)和达到的最高温度对该过程所得能量比(ER)以及所获水炭燃料特性的影响。使用标准化生物废料原料进行了十次实验。测试了不同的固体含量(重量百分比分别为2.54%、4.93%、7.44%、9.45%、12.83%、15.2%)和不同的目标最高温度(170°C、180°C、190°C、200°C)。与原料相比,所有所得水炭的高热值(HHV)(平均为29.2 MJ/kg)和碳含量(平均为66.9%)均高于原始生物废料(分别为19.3 MJ/kg和46.2%)。所获得的高热值与木炭的高热值(29.6 MJ/kg)相似。较高的固体含量导致较高的水炭产率和碳效率,而较高的温度导致水炭的碳含量和高热值更高。固体含量最高(15.2%)的实验实现了能量比>1。