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通过对基于 BaTiO/PDMS 的摩擦电纳米发电机进行后极化技术来提高输出性能。

Enhancement of output performance through post-poling technique on BaTiO/PDMS-based triboelectric nanogenerator.

机构信息

State Key Lab for Modification of Chemical Fibers & Polymer Materials, College of Materials Science & Engineering, Donghua University, Shanghai, 201620, People's Republic of China.

出版信息

Nanotechnology. 2017 Feb 17;28(7):075203. doi: 10.1088/1361-6528/aa52b7. Epub 2017 Jan 13.

Abstract

In the modern era, the invention of new energy sources is important in order to make advances possible in electronic media. A triboelectric nanogenerator (TENG) is considered to be strong design that converts mechanical power into electrical power, using organic (polymer) or inorganic (lead, ceramic etc) materials to initiate the triboelectrification process, followed by charge separation. In this study, a lead-free BaTiO/PDMS-Al-based TENG was fabricated by mixing tetragonal ferroelectric BaTiO nanocrystals in a PDMS matrix to make a composite for a working electrode film. It is worth noting that a new post- poling process has been introduced to align the dipole structures in the BaTiO nanocrystals, and to attain a high electron density on the surface of the working electrode film. The output was recorded up to 375 V and 6 μA of close circuit voltage and short circuit current, respectively, at a current density of 0.3 μA cm and an effective power equal to 2.25 mW at a load resistance of 100 MΩ, and is four times higher than a PDMS-Al-based TENG. This study also reveals the hidden locks that will enable other inorganic materials with a dipole structure to enhance their output using the post-poling technique. The TENG has a vast field of applications due to its stability, the flexibility of its thin films and its biocompatibility. It is also an aid for exploring new TENG devices with enhanced output performance.

摘要

在现代,发明新能源对于电子媒体的进步很重要。摩擦纳米发电机(TENG)被认为是一种强大的设计,可以将机械能转化为电能,使用有机(聚合物)或无机(铅、陶瓷等)材料来启动摩擦带电过程,然后进行电荷分离。在这项研究中,通过将四方铁电 BaTiO 纳米晶混合到 PDMS 基体中,制备了一种无铅 BaTiO/PDMS-Al 基 TENG,用于制造工作电极膜的复合材料。值得注意的是,引入了一种新的后极化工艺来对齐 BaTiO 纳米晶中的偶极结构,并在工作电极膜的表面获得高电子密度。在电流密度为 0.3 μA cm 时,开路电压和短路电流分别记录高达 375 V 和 6 μA,有效功率等于 100 MΩ 负载电阻时的 2.25 mW,是 PDMS-Al 基 TENG 的四倍。本研究还揭示了隐藏的锁,将使其他具有偶极结构的无机材料能够利用后极化技术提高其输出。由于其稳定性、薄膜的柔韧性和生物相容性,TENG 具有广阔的应用领域。它也是探索具有增强输出性能的新型 TENG 器件的辅助工具。

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