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一种基于浸渍有ZIF-8纳米晶体的柔性透明薄膜的复合摩擦纳米发电机。

A composite triboelectric nanogenerator based on flexible and transparent film impregnated with ZIF-8 nanocrystals.

作者信息

Wen Rongmei, Fan Liming, Li Qiaoling, Zhai Junyi

机构信息

Department of Chemistry, College of Science, North University of China, Taiyuan 030051, People's Republic of China.

Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People's Republic of China.

出版信息

Nanotechnology. 2021 Jun 3;32(34). doi: 10.1088/1361-6528/ac020f.

Abstract

The triboelectric nanogenerator (TENG), based on the triboelectrification coupled with electrostatic induction, can directly convert ambient mechanical energy into electric energy. However, the output performance of TENG is still low and demands further improvement to speed up the commercial application. In this work, we demonstrate a TENG based on a flexible and transparent composite film made of PDMS and ZIF-8. When the amount of the ZIF-8 is 4 wt%, the generated output current and voltage of the TENG are gradually increased up to 16.3A and 176 V, which are 210% and 230% higher than that of TENG without ZIF-8, respectively. Impregnated ZIF-8 which exhibits a positive polarity lowers the effective work function of the PDMS and enhance the surface charge density, verified by Kelvin probe force microscope measurement.

摘要

摩擦纳米发电机(TENG)基于摩擦起电并耦合静电感应,能够直接将环境机械能转化为电能。然而,TENG的输出性能仍然较低,需要进一步改进以加速其商业应用。在这项工作中,我们展示了一种基于由聚二甲基硅氧烷(PDMS)和ZIF-8制成的柔性透明复合膜的TENG。当ZIF-8的含量为4 wt%时,TENG产生的输出电流和电压逐渐增加至16.3A和176 V,分别比不含ZIF-8的TENG高210%和230%。通过开尔文探针力显微镜测量验证,呈现正极性的浸渍ZIF-8降低了PDMS的有效功函数并提高了表面电荷密度。

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