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日本含全氟辛烷磺酸水成膜泡沫库存数量的重新评估:库存调查中的差距与陷阱

Revaluation of stockpile amount of PFOS-containing aqueous film-forming foam in Japan: gaps and pitfalls in the stockpile survey.

作者信息

Zushi Yasuyuki, Yamamoto Atsushi, Tsunemi Kiyotaka, Masunaga Shigeki

机构信息

National Institute of Advanced Industrial Science and Technology, 16-1 Onogawa, Tsukuba, Ibaraki, 305-8506, Japan.

Tottori University of Environmental Studies, Tottori, Japan.

出版信息

Environ Sci Pollut Res Int. 2017 Mar;24(7):6736-6745. doi: 10.1007/s11356-017-8374-1. Epub 2017 Jan 13.

Abstract

Stockpiles of perfluoro-octane sulfonic acid (PFOS) containing aqueous film-forming foam (AFFF) have the potential to be emitted by leaching, spills, and during use in fire response and other processes. Several studies have discussed the high levels of stockpiled PFOS-containing AFFF and the risk they pose to the environment; however, there are large gaps in the amounts in Japan compared with other countries. For example, 300 tons are stockpiled in Canada, 2200-2600 tons in Switzerland, 1400 tons in Norway, and 19,000 tons in Japan from their reports for publication. The gap is considered to be a result of lack of surveys of several important sources. In this study, we revaluated the stockpile of AFFF in Japan to verify the reported value and identify the source of this gap based on information available in peer-reviewed papers, governmental reports, and business reports. The major reason for the gap between Japan and other countries was considered to be the survey of stockpiles in car-parking facilities, which accounted for 46.7% of the total amounts in Japan, but were not considered in other countries. These stockpiles indicate a high potential for accidental leaching or spilling of the AFFF by careless storage. Therefore, it is recommended that continual surveys of the AFFF stockpile in car-parking facilities be conducted in the rest of the world.

摘要

含有全氟辛烷磺酸(PFOS)的水成膜泡沫灭火剂(AFFF)库存,有可能通过沥滤、泄漏以及在灭火和其他过程中使用时释放出来。多项研究探讨了大量储存的含PFOS的AFFF及其对环境构成的风险;然而,与其他国家相比,日本的此类物质数量存在很大差距。例如,根据已发表的报告,加拿大储存了300吨,瑞士储存了2200 - 2600吨,挪威储存了1400吨,而日本储存了19000吨。这种差距被认为是由于对几个重要来源缺乏调查所致。在本研究中,我们重新评估了日本的AFFF库存,以核实报告值,并根据同行评审论文、政府报告和商业报告中的现有信息确定这种差距的来源。日本与其他国家之间存在差距的主要原因被认为是对停车场设施中库存的调查,停车场设施中的库存占日本总量的46.7%,但其他国家未考虑这部分。这些库存表明,由于储存不当,AFFF存在意外沥滤或泄漏的高风险。因此,建议世界其他地区对停车场设施中的AFFF库存进行持续调查。

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