State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China.
Department of Chemistry, Brown University, Providence, RI 02912, USA.
Nanoscale. 2017 Feb 2;9(5):1909-1915. doi: 10.1039/c6nr09200d.
Carbon dots (CDs) usually emit a strong blue light and excitation wavelength dependent long wavelength lights. This significantly limits their applications because one has to use a series of different excitation light sources to get different colors and the long wavelength emissions are usually very weak. We found that one type of CDs synthesized from p-phenylenediamine could emit various long wavelength lights (green to red) independent of the excitation wavelength when dispersed in different solvents. The photoluminescence quantum yields of the same CDs were 10-35% in different solvents for different color emissions. Based on this solvent-color effect, we further mixed the same CDs with different polymers to form solid CD films for various color emissions, and these film emissions were also excitation wavelength independent. Multicolor LEDs were demonstrated with the same CDs in solution and solid film states for color displays.
碳点(CDs)通常发射强蓝光和激发波长依赖的长波长光。这极大地限制了它们的应用,因为人们必须使用一系列不同的激发光源来获得不同的颜色,而且长波长发射通常非常弱。我们发现,由对苯二胺合成的一种类型的 CDs 在分散在不同溶剂中时,可以独立于激发波长发射各种长波长光(绿色到红色)。对于不同颜色的发射,相同 CDs 在不同溶剂中的光致发光量子产率为 10-35%。基于这种溶剂-颜色效应,我们进一步将相同的 CDs 与不同的聚合物混合形成用于各种颜色发射的固态 CD 薄膜,并且这些薄膜发射也与激发波长无关。我们使用相同的 CDs 在溶液和固态薄膜状态下展示了多色 LED,用于颜色显示。