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可清洗空气过滤器能传递湿气并有效捕获 PM。

Cleanable Air Filter Transferring Moisture and Effectively Capturing PM.

机构信息

Key Laboratory of Textile Science and Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai, 201620, China.

Nanofibers Research Center, Modern Textile Institute, Donghua University, Shanghai, 200051, China.

出版信息

Small. 2017 Mar;13(11). doi: 10.1002/smll.201603306. Epub 2017 Jan 17.

DOI:10.1002/smll.201603306
PMID:28094471
Abstract

The lethal danger of particulate matter (PM) pollution on health leads to the development of challenging individual protection materials that should ideally exhibit a high PM purification efficiency, low air resistance, an important moisture-vapor transmission rate (MVTR), and an easy-to-clean property. Herein, a cleanable air filter able to rapidly transfer moisture and efficiently capture PM is designed by electrospinning superhydrophilic polyacrylonitrile/silicon-dioxide fibers as the adsorption-desorption vector for moisture-vapor, and hydrophobic polyvinylidene fluoride fibers as the repellent components to avoid the formation of capillary water under high humidity. The desorption rate of water molecules increases from 10 to 18 mg min , while the diameters of polyacrylonitrile fibers reduce from 1.02 to 0.14 µm. Significantly, by introducing the hydroxyl on the surface of polyacrylonitrile nanofibers, rapid adsorption-desorption of the water molecules is observed. Moreover, by constructing a hydrophobic to super-hydrophilic gradient structure, the MVTR increases from 10 346 to 14 066 g m d . Interestingly, the prepared fibrous membranes is easy to clean. More importantly, benefiting from enhanced slip effect, the resultant fibrous membranes presented a low air resistance of 86 Pa. A field test in Shanghai shows that the air filter maintains stable PM purification efficiency of 99.99% at high MVTR during haze event.

摘要

颗粒物(PM)污染对健康的致命危害导致了具有挑战性的个人防护材料的发展,这些材料理想情况下应表现出高的 PM 净化效率、低空气阻力、重要的水汽传输率(MVTR)和易于清洁的特性。在此,通过静电纺丝超亲水聚丙烯腈/二氧化硅纤维作为水汽的吸附-解吸载体,疏水性聚偏二氟乙烯纤维作为排斥成分,设计了一种可清洁的空气过滤器,能够快速传递水分并有效地捕获 PM。水分子的解吸速率从 10 增加到 18 mg min ,而聚丙烯腈纤维的直径从 1.02 减小到 0.14 µm。值得注意的是,通过在聚丙烯腈纳米纤维表面引入羟基,可以观察到水分子的快速吸附和解吸。此外,通过构建疏水到超亲水的梯度结构,MVTR 从 10 346 增加到 14 066 g m d 。有趣的是,制备的纤维膜易于清洁。更重要的是,由于增强的滑移效应,所得纤维膜的空气阻力低至 86 Pa。在上海的现场测试表明,空气过滤器在高 MVTR 下的霾事件中保持稳定的 PM 净化效率 99.99%。

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