Li Yuyao, Hua Yuezhen, Ji Zekai, Wu Zheng, Fan Jie, Liu Yong
State Key Laboratory of Separation Membranes and Membrane Processes, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China.
Nantong Bolian Material Technology Co, Ltd, Nantong, 226010, China.
J Memb Sci. 2023 Apr 15;672:121257. doi: 10.1016/j.memsci.2022.121257. Epub 2022 Dec 29.
Coronavirus disease 2019 (COVID-19) pandemic makes protective respirators highly demanded. The respirator materials should filter out viral fine aerosols effectively, allow airflow to pass through easily, and wick away the exhalant moisture timely. However, the commonly used melt-blown nonwovens perform poorly in meeting these requirements simultaneously. Herein, dual-bionic nano-groove structured (NGS) nanofibers are fabricated to serve as protective, breathable and moisture-wicking respirator materials. The creativity of this design is that the tailoring of dual-bionic nano-groove structure, combined with the strong polarity and hydrophilicity of electrospinning polymer, not only endows the nanofibrous materials with improved particle capture ability but also enable them to wick away and transmit breathing moisture. Benefitting from the synthetic effect of hierarchical structure and the intrinsic property of polymers, the resulting NGS nanofibrous membranes show a high filtration efficiency of 99.96%, a low pressure drop of 110 Pa, and a high moisture transmission rate of 5.67 kg m d at the same time. More importantly, the sharp increase of breathing resistance caused by the condensation of exhaled moisture is avoided, overcoming the bottleneck faced by traditional nonwovens and paving a new way for developing protective respirators with high wear comfortability.
2019年冠状病毒病(COVID-19)大流行使得防护口罩的需求大增。口罩材料应能有效过滤病毒细气溶胶,使气流易于通过,并及时吸除呼出的湿气。然而,常用的熔喷无纺布在同时满足这些要求方面表现不佳。在此,制备了具有双仿生纳米槽结构(NGS)的纳米纤维,用作防护、透气和吸湿排汗的口罩材料。该设计的创新之处在于,双仿生纳米槽结构的剪裁,结合静电纺丝聚合物的强极性和亲水性,不仅赋予纳米纤维材料更高的颗粒捕获能力,还使其能够吸除并传导呼吸湿气。受益于分级结构的综合效应和聚合物的固有特性,所得的NGS纳米纤维膜同时具有99.96%的高过滤效率、110 Pa的低压降和5.67 kg m⁻² d⁻¹的高透湿率。更重要的是,避免了呼出湿气凝结导致的呼吸阻力急剧增加,克服了传统无纺布面临的瓶颈,为开发具有高佩戴舒适性的防护口罩开辟了新途径。