CEMES-CNRS , 29 Rue J. Marvig, 31055 Toulouse, France.
Université de Toulouse, UPS, CNRS, CEMES , 118 route de Narbonne, 31062 Toulouse, France.
Chem Rev. 2017 Feb 8;117(3):1407-1444. doi: 10.1021/acs.chemrev.6b00389. Epub 2017 Jan 18.
This review aims at giving the readers the basic concepts needed to understand two-dimensional bimolecular organizations at the vacuum-solid interface. The first part describes and analyzes molecules-molecules and molecules-substrates interactions. The current limitations and needs in the understanding of these forces are also detailed. Then, a critical analysis of the past and recent advances in the field is presented by discussing most of the key papers describing bicomponents self-assembly on solid surface in an ultrahigh vacuum environment. These sections are organized by considering decreasing molecule-molecule interaction strengths (i.e. starting from strong directional multiple H bonds up to weaker nondirectional bonds taking into account the increasing fundamental role played by the surface). Finally, we conclude with some research directions (predicting self-assembly, multi-components systems, and nonmetallic surfaces) and potential applications (porous networks and organic surfaces).
本文旨在为读者提供理解真空-固界面二维双分子结构所需的基本概念。第一部分描述和分析了分子-分子和分子-基底相互作用。还详细说明了目前对这些力的理解的局限性和需求。然后，通过讨论大多数描述在超高真空环境下固体表面双组分自组装的关键论文，对该领域过去和近期的进展进行了批判性分析。这些部分是通过考虑降低分子-分子相互作用强度（即从强的方向性多重氢键开始，到考虑表面的作用越来越重要而较弱的非方向性键）来组织的。最后，我们总结了一些研究方向（预测自组装、多组分体系和非金属表面）和潜在应用（多孔网络和有机表面）。
