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用于核认证参考材料的醋酸丁酸纤维素薄膜的长期稳定性

Long-term stability of cellulose acetate butyrate thin films for nuclear certified reference materials.

作者信息

Buják Renáta, Delva Laurens, Erkoç Mustafa, Bauwens Jeroen, Jakopič Rožle, Vincze Laszlo, Aregbe Yetunde, Cardon Ludwig

机构信息

Directorate G: Nuclear Safety & Security, Joint Research Centre, European Commission, Retieseweg 111, 2440 Geel, Belgium.

Centre for Polymer & Material Technologies (CPMT), Faculty of Engineering and Architecture, Ghent University, Technologiepark 915, 9052 Zwijnaarde, Belgium.

出版信息

J Radioanal Nucl Chem. 2017;311(1):877-886. doi: 10.1007/s10967-016-5083-z. Epub 2016 Oct 27.

DOI:10.1007/s10967-016-5083-z
PMID:28111490
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5219040/
Abstract

Characterization of cellulose acetate butyrate (CAB) thin films with 17, 35 and 52 wt% butyryl is carried out to select the most suitable matrix material for the U and Pu containing large-sized dried spike reference material. The virgin CAB samples were aged by vibrations, heat, humidity, UV light and X-rays. Characterization was done by thermo-analytical techniques, gel permeation chromatography, mechanical tests and via Rayleigh and Compton scattering. The results show that CAB with lower butyryl content can withstand higher operational temperatures and has greater mechanical strength while CAB with higher butyryl content seems to be more resistant to radiation.

摘要

对丁酰基含量分别为17%、35%和52%的醋酸丁酸纤维素（CAB）薄膜进行了表征，以选择最适合用于含铀和钚的大尺寸干燥尖峰参考材料的基质材料。原始CAB样品通过振动、加热、湿度、紫外线和X射线进行老化处理。通过热分析技术、凝胶渗透色谱法、力学测试以及瑞利散射和康普顿散射进行表征。结果表明，丁酰基含量较低的CAB能够承受更高的工作温度且具有更大的机械强度，而丁酰基含量较高的CAB似乎对辐射更具抗性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/181d58d02e82/10967_2016_5083_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/ce0fcfc60bd8/10967_2016_5083_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6a1ad44e6b4c/10967_2016_5083_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/87d5efb6d747/10967_2016_5083_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/dbbaa0ae821e/10967_2016_5083_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/df881aa43be3/10967_2016_5083_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6ca99b87c051/10967_2016_5083_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/8d60486eb9c9/10967_2016_5083_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6f3e2b5e46be/10967_2016_5083_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/7e9641969758/10967_2016_5083_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/181d58d02e82/10967_2016_5083_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/ce0fcfc60bd8/10967_2016_5083_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6a1ad44e6b4c/10967_2016_5083_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/87d5efb6d747/10967_2016_5083_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/dbbaa0ae821e/10967_2016_5083_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/df881aa43be3/10967_2016_5083_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6ca99b87c051/10967_2016_5083_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/8d60486eb9c9/10967_2016_5083_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/6f3e2b5e46be/10967_2016_5083_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/7e9641969758/10967_2016_5083_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7409/5219040/181d58d02e82/10967_2016_5083_Fig10_HTML.jpg

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3
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